Stellite 21

Stellite 21 is a cobalt-chromium alloy with excellent corrosion resistance, thermal stability, and wear resistance, suitable for high-temperature and harsh environments.

About Stellite 21

Name and Equivalent Name: Stellite 21, also known as Cobalt-Chromium Alloy 21, holds the UNS designation R30021. It conforms to ASTM F75, B426, B659, and AMS 5846 standards, with international equivalents such as DIN/EN 2.4973 and GB/T 15025: CoCrW21. It is also approved under ASME SB-75 and ISO 5832-4 and complies with NACE MR0175 for corrosion-resistant applications.

Stellite 21 Basic Introduction

Stellite 21 is a high-performance cobalt-chromium alloy with excellent corrosion resistance, wear resistance, and mechanical stability at elevated temperatures. It contains molybdenum to enhance strength and corrosion protection, making it suitable for aggressive environments, including chemical processing, marine, and oil & gas applications.

This alloy excels in demanding conditions with mechanical stress and chemical exposure. Stellite 21’s ability to retain its properties under elevated temperatures and its resistance to thermal fatigue make it a preferred material for valves, seals, and other critical components in high-temperature systems.

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Alternative Superalloys of Stellite 21

While Stellite 21 balances wear and corrosion resistance, other superalloys may be preferred in certain situations. Stellite 6 offers better wear resistance but less corrosion protection, making it ideal for applications focused on abrasion. Stellite 12 is harder, offering enhanced abrasion resistance but less flexibility.

Inconel 718 and Hastelloy C22 enhance oxidation resistance for more extreme high-temperature environments. Nimonic 75 and Rene 41 are excellent for aerospace applications requiring thermal fatigue resistance and long-term creep performance.


Stellite 21 Design Intention

Stellite 21 was designed for corrosion resistance, mechanical durability, and thermal stability. The primary goal of this alloy is to offer a balance of wear resistance and toughness, ensuring longevity under elevated temperatures. It is particularly well-suited for applications requiring both mechanical performance and chemical resistance.

The alloy is used in critical components, such as valve seats, seals, and turbine parts, where it withstands high mechanical loads and chemical exposure. Stellite 21’s formulation reduces maintenance needs, making it ideal for industries where downtime is costly, including energy, oil & gas, and aerospace sectors.


Stellite 21 Chemical Composition

The chemical composition of Stellite 21 incorporates chromium for corrosion resistance, molybdenum for strength, and low carbon content for improved ductility. These elements work together to ensure excellent wear resistance without sacrificing mechanical flexibility.

Element

Composition (%)

Cobalt (Co)

Balance

Chromium (Cr)

27.0-29.0

Molybdenum (Mo)

5.0-6.0

Carbon (C)

Max 0.20

Nickel (Ni)

2.0-3.0

Silicon (Si)

Max 1.0

Manganese (Mn)

Max 1.0

Iron (Fe)

Max 2.0


Stellite 21 Physical Properties

Stellite 21 offers thermal stability and reliable performance under mechanical stress, making it suitable for high-temperature and corrosive environments.

Property

Value

Density (g/cm³)

8.33

Melting Point (°C)

1325

Thermal Conductivity (W/(m·K))

11.9

Elastic Modulus (GPa)

205


Metallographic Structure of Stellite 21 Superalloy

Stellite 21 features a cobalt-based matrix with finely distributed chromium and molybdenum carbides, which provide excellent wear resistance. The carbides enhance the alloy's ability to maintain mechanical properties under abrasive conditions, extending the lifespan of components.

The chromium content forms a protective oxide layer, improving the alloy’s corrosion resistance. The low carbon content helps maintain toughness, while molybdenum contributes to strength and corrosion protection, making the alloy suitable for harsh environments with thermal fluctuations and chemical exposure.


Stellite 21 Mechanical Properties

Stellite 21 provides high tensile and yield strength, good creep resistance, and reliable fatigue performance, ensuring long-term durability in demanding environments.

Property

Value

Tensile Strength (MPa)

850-900

Yield Strength (MPa)

500-600

Creep Strength

Good for elevated temperatures

Hardness (HRC)

45-50

Elongation (%)

~10%

Modulus of Elasticity (GPa)

210


Key Features of Stellite 21 Superalloy

  1. High Corrosion Resistance Stellite 21 offers excellent corrosion resistance, especially in marine and chemical environments. The alloy’s protective oxide layer ensures longevity in corrosive settings, making it ideal for valves, seals, and chemical processing equipment.

  2. Thermal Stability The alloy maintains mechanical strength and stability under high temperatures, making it suitable for components like turbine parts and heat exchangers. It also exhibits good creep resistance, ensuring performance over extended periods.

  3. Wear Resistance Stellite 21 provides reliable wear resistance, even under abrasive conditions. This makes it a preferred material for valve seats and pump components used in industries where mechanical stress is high.

  4. Toughness and Ductility With low carbon content, Stellite 21 maintains good ductility and toughness, enabling it to withstand mechanical shock and stress without cracking. This property ensures durability in components subject to impact loads.

  5. Long Service Life Designed for harsh environments, Stellite 21 offers long service life with minimal maintenance. Its ability to resist wear, corrosion, and thermal fatigue ensures that components remain operational for extended periods, reducing downtime and maintenance costs.

Stellite 21 Superalloy’s Machinability and Processing

  • Vacuum Investment Casting: Stellite 21 performs well in vacuum investment casting, offering excellent corrosion resistance and dimensional stability. This process minimizes oxidation, ensuring precise components for high-performance applications.

  • Single Crystal Casting: Stellite 21 is not ideal for single crystal casting due to carbide formation, which disrupts the uniform grain structure necessary for this process, limiting its use in applications requiring high directional strength.

  • Equiaxed Crystal Casting: Equiaxed crystal casting is suitable for Stellite 21, providing uniform microstructures that enhance wear resistance and mechanical performance. This makes it ideal for valve seats and pump components.

  • Superalloy Directional Casting: Stellite 21 is not typically used in directional casting since it lacks the required grain alignment properties. It is better suited for static applications requiring high corrosion resistance.

  • Powder Metallurgy Turbine Disc: Stellite 21 offers excellent corrosion resistance, but it is less common in powder metallurgy turbine discs due to moderate creep resistance than other high-temperature superalloys.

  • Superalloy Precision Forging: Stellite 21 is not commonly used for precision forging due to its inherent hardness, but it performs well in overlays and hard-facing applications that enhance wear resistance.

  • Superalloy 3D Printing: Stellite 21 is challenging to 3D print due to its tendency to form carbides, but advanced post-processing techniques can improve its mechanical properties for specialized applications.

  • CNC Machining: Stellite 21 is suitable for CNC machining, although its hardness can wear down cutting tools quickly. Specialized tooling and techniques are recommended to achieve precision.

  • Superalloy Welding: Stellite 21 exhibits excellent weldability and is widely used for hard-facing applications. Welded components deliver high corrosion resistance and extended service life.

  • Hot Isostatic Pressing (HIP): HIP processing eliminates porosity in Stellite 21, improving mechanical integrity. This process ensures consistent performance in components exposed to thermal cycling and stress.


Stellite 21 Superalloy Applications

  • Aerospace and Aviation: Stellite 21 is used for valve seats, fuel nozzles, and other components where corrosion resistance and thermal stability are critical.

  • Power Generation: The alloy is ideal for steam turbines and heat exchangers, ensuring long service life with minimal corrosion and wear under high temperatures.

  • Oil and Gas: Stellite 21 is commonly used in valves, pipelines, and drill bits due to its ability to resist corrosion and abrasion in harsh environments.

  • Energy: In the energy sector, the alloy ensures reliable performance in gas turbines and power plants, even under extreme thermal cycling.

  • Marine: Stellite 21 is used for pump shafts, valves, and propellers, offering excellent corrosion resistance in marine environments.

  • Mining: The alloy’s wear resistance makes it suitable for mining equipment, including crushers, drill bits, and slurry pumps, extending operational life.

  • Automotive: Stellite 21 is used for high-performance exhaust valves and other components exposed to thermal fatigue in automotive engines.

  • Chemical Processing: The alloy is employed in chemical processing equipment, resisting aggressive chemicals and high temperatures.

  • Pharmaceutical and Food: Stellite 21 ensures contamination-free pharmaceutical and food processing equipment surfaces, withstanding cleaning agents and sterilization.

  • Military and Defense: The alloy’s toughness and corrosion resistance are ideal for military components, including missile systems and protective coatings.

  • Nuclear: Stellite 21 is used in valves, pumps, and seals in nuclear reactors, providing long-term stability under radiation and thermal cycling.


When to Choose Stellite 21 Superalloy

Custom superalloy parts like Stellite 21 are ideal for wear resistance, corrosion protection, and thermal stability applications. It is especially effective in harsh environments such as aerospace, chemical processing, and marine industries, where components are exposed to extreme temperatures and aggressive chemicals.

Stellite 21 is the right choice for applications requiring minimal maintenance and long-term durability. Its weldability makes it ideal for hard-facing and overlay applications, while its corrosion resistance ensures reliable performance in chemical reactors and nuclear plants. If you need a material that can withstand abrasive conditions without losing mechanical integrity, Stellite 21 is an excellent option.

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